Titanium(IV) chloride ReagentPlus, trace metals basis, 200g

SKU:
208566-200G
  • $77.10

    • Description

    Titanium(IV) chloride

    ReagentPlus®, 99.9% trace metals basis

    Synonym(s):
    TTC, Titanium tetrachloride
    Linear Formula:
    TiCl4
    CAS Number:
    7550-45-0
    Molecular Weight:
    189.68
    EC Number:
    231-444-5
    MDL number:
    MFCD00011267
    PubChem Substance ID:
    329752044
    NACRES:
    NA.55

    PROPERTIES

    vapor pressure

    50 mmHg ( 55 °C)
    9.6 mmHg ( 20 °C)

    Quality Level

    100
    200

    product line

    ReagentPlus®

    Assay

    99.9% trace metals basis

    form

    liquid

    reaction suitability

    reagent type: catalyst
    core: titanium

    bp

    135-136 °C (lit.)

    mp

    −25 °C (lit.)

    density

    1.73 g/mL at 20 °C (lit.)

    SMILES string

    Cl[Ti](Cl)(Cl)Cl

    InChI

    1S/4ClH.Ti/h4*1H;/q;;;;+4/p-4

    InChI key

    XJDNKRIXUMDJCW-UHFFFAOYSA-J

    DESCRIPTION

    General description

    Titanium(IV) chloride participates in the Baylis-Hillman reaction of arylaldehydes with methyl vinyl ketone.[1] Neutral solutions of TiCl4 having a pH in the range of 2.5 to 6.0 (prepared by the addition of magnesium oxide as a base) have been used for the synthesis of nanosized titanium dioxide.[2]

    Application

    Activates pyrrolidines for improved conversion, via a modified Bouveault reaction, to the corresponding α,α-dimethylamines.[3]
    Along with sodium borohydride, it forms an effective reagent for the reduction of:[4]
    • carboxylic acid and acyl chloride to alcohols
    • carboxamides, oximes and lactams to amines
    • sulfoxides to sulfides
    Titanium(IV) chloride (TiCl4) has been used as a precursor for the synthesis of Ag-TiO2@polyethylene glycol (PEG) nanoparticles.[5] TiCl4 may also be used as one of the constituents to synthesize TiO2/Al2O3 binary oxide materials[6] and N-(10-oxo-vinylanthracen-9-(10H)-ylidene)cyanamide.[7]

    Legal Information

    ReagentPlus is a registered trademark of Sigma-Aldrich Co. LLC

    SAFETY INFORMATION

    Signal Word

    Danger

    Hazard Statements

    H314 - H330 - H335

    Precautionary Statements

    P260 - P271 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

    Hazard Classifications

    Acute Tox. 1 Inhalation - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

    Target Organs

    Respiratory system

    Supplementary Hazards

    EUH014

    Storage Class Code

    6.1B - Non-combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials

    WGK

    WGK 1

    Flash Point(F)

    Not applicable

    Flash Point(C)

    Not applicable