alpha-Phellandrene (1mL)

SKU:
77429-1ML
$93.70

Description

77429 Sigma-Aldrich

(R)-(−)-α-Phellandrene

≥95.0% (sum of enantiomers, GC)

Synonym: (−)-p-Mentha-1,5-diene, (R)-(-)-alpha-Phellandrene, (R)-5-Isopropyl-2-methyl-1,3-cyclohexadiene

  • CAS Number 4221-98-1

     
  • Empirical Formula (Hill Notation) C10H16

     
  • Molecular Weight 136.23

     
  •  Beilstein Registry Number 2497824

     
  •  EC Number 224-167-6

  •  MDL number MFCD00062988

     

Description

Packaging

1, 5 mL in glass bottle

Application

(R)-(-)-α-Phellandrene undergoes [4+2] cycloaddition with 2-naphthyl acetylenecarboxylate to form a chiral diene, which can act as a ligand for the rhodium-catalyzed asymmetric addition reactions.[2] It may be used to synthesize (1S,5R)-5-(1-methylethyl)-2-methylidene-3-cyclohexen-1-yl hydroperoxide, which on reduction forms trans-yabunikkeol.[3]

General description

(R)-(-)-α-Phellandrene is a monoterpene derivative.[1]

Properties

Related Categories Alkenes, Allium sativum (Garlic), Artemisia vulgaris,Asymmetric Synthesis, Boswellia carterii,
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InChI Key OGLDWXZKYODSOB-SNVBAGLBSA-N
assay ≥95.0% (sum of enantiomers, GC)
optical activity [α]20/D −225±5°, c = 10% in diethyl ether
bp 171-174 °C(lit.)
density 0.844 g/mL at 20 °C(lit.)
storage temp. 2-8°C