Lithium aluminum hydride solution, 100ML

SKU:
593702-100ML
  • $81.60

    • Description

    Lithium aluminum hydride solution, 100ML

    2.0 M in THF

    Synonym(s):
    Lithium tetrahydroaluminate, LAH, Lithium alanate
    Linear Formula:
    LiAlH4
    CAS Number:
    16853-85-3
    Molecular Weight:
    37.95
    MDL number:
    MFCD00011075
    PubChem Substance ID:
    24881465
    NACRES:
    NA.22

    PROPERTIES

    Quality Level

    200

    reaction suitability

    reagent type: reductant

    concentration

    2.0 M in THF

    density

    0.906 g/mL at 25 °C

    storage temp.

    2-30°C

    SMILES string

    [Li+].[AlH4-]

    InChI

    1S/Al.Li.4H/q-1;+1;;;;

    InChI key

    OCZDCIYGECBNKL-UHFFFAOYSA-N

    Application

    Reactant or reagent for:
    • The preparation of thermoplastic polyester polyamides from oleic acid
    • Lithium-polymer batteries
    • Hydrodefluorination of gem-difluoromethylene derivatives
    • Asymmetric aldol reactions
    • Synthesis of Li-Al-N-H composites with hydrogen absorption / desorption properties

    LAH is a powerful reducing agent for many different reduction reactions such as that of ketones to alcohols

    Packaging

    4×25, 100 mL in Sure/Seal™
    The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

    Legal Information

    Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

    SAFETY INFORMATION

    Signal Word

    Danger

    Hazard Statements

    H225 - H260 - H302 - H314 - H335 - H336 - H351

    Precautionary Statements

    P210 - P231 + P232 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

    Hazard Classifications

    Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - Water-react. 1

    Supplementary Hazards

    EUH019

    Storage Class Code

    4.3 - Hazardous materials, which set free flammable gases upon contact with water

    WGK

    WGK 1

    Flash Point(F)

    -13.0 °F - closed cup

    Flash Point(C)

    -25 °C - closed cup

    Personal Protective Equipment

    dust mask type N95 (US), Eyeshields, Gloves