Camphorsulfonic acid, 5G

SKU:
C2107-5G
  • $31.00

    • Description

    (1S)-(+)-10-Camphorsulfonic acid, 5G

    Synonym(s):
    (+)-Camphor-10-sulfonic acid (β), (1S)-Camphor-10-sulfonic acid
    Empirical Formula (Hill Notation):
    C10H16O4S
    CAS Number:
    3144-16-9
    Molecular Weight:
    232.30
    Beilstein:
    2809675
    EC Number:
    221-554-1
    MDL number:
    MFCD00064157
    PubChem Substance ID:
    24892465
    NACRES:
    NA.22

    PROPERTIES

    Quality Level

    200

    Assay

    99%

    form

    crystals

    optical activity

    [α]20/D +19.9°, c = 2 in H2O

    mp

    196-200 °C (dec.) (lit.)

    SMILES string

    CC1(C)[C@@H]2CC[C@@]1(CS(O)(=O)=O)C(=O)C2

    InChI

    1S/C10H16O4S/c1-9(2)7-3-4-10(9,8(11)5-7)6-15(12,13)14/h7H,3-6H2,1-2H3,(H,12,13,14)/t7-,10-/m1/s1

    InChI key

    MIOPJNTWMNEORI-GMSGAONNSA-N

    Application

    (1S)-(+)-10-Camphorsulfonic acid may be used as a starting material to synthesize 10-iodocamphor.[1] It may also be used as a dopant to induce chirality in the conduction band of polyaniline.[2] (±)-S-methyl-S-phenylsulfoximine can be resolved using it as a chiral resolving agent to form the (-)-form in high enantiomeric purity.[3]
    Used as a resolving agent,[4] as a catalyst for coupling dipeptides.[5]

    SAFETY INFORMATION

    Pictograms

    GHS05

    Signal Word

    Danger

    Hazard Statements

    H290 - H314

    Precautionary Statements

    P234 - P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

    Hazard Classifications

    Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B

    Storage Class Code

    8A - Combustible, corrosive hazardous materials

    WGK

    WGK 3

    Flash Point(F)

    Not applicable

    Flash Point(C)

    Not applicable

    Personal Protective Equipment

    dust mask type N95 (US), Eyeshields, Gloves