Boron trifluoride diethyl etherate, 1L

SKU:
175501-1L
  • $128.00

    • Description

    Boron trifluoride diethyl etherate, 1L

    for synthesis

    Synonym(s):
    Boron trifluoride ethyl etherate
    Linear Formula:
    BF3 · O(C2H5)2
    CAS Number:
    109-63-7
    Molecular Weight:
    141.93
    Beilstein:
    3909607
    EC Number:
    203-689-8
    MDL number:
    MFCD00013194
    PubChem Substance ID:
    24850505
    NACRES:
    NA.22

    PROPERTIES

    grade

    for synthesis

    Quality Level

    200

    vapor density

    4.9 (vs air)

    vapor pressure

    4.2 mmHg ( 20 °C)

    form

    liquid

    expl. lim.

    36 %

    reaction suitability

    core: boron
    reagent type: Lewis acid
    reagent type: catalyst

    refractive index

    n20/D 1.344 (lit.)

    bp

    126-129 °C (lit.)

    mp

    −58 °C (lit.)

    density

    1.15 g/mL (lit.)

    storage temp.

    2-8°C

    SMILES string

    CC[O+](CC)[B-](F)(F)F

    InChI

    1S/C4H10BF3O/c1-3-9(4-2)5(6,7)8/h3-4H2,1-2H3

    Inchi Key

    MZTVMRUDEFSYGQ-UHFFFAOYSA-N

    DESCRIPTION

    General description

    Boron trifluoride diethyl etherate or boron trifluoride-ether complex is an organic compound widely used as a convenient source of boron trifluoride (BF3) in organic synthesis. It is also used as a Lewis acid for the activation of electrophiles.

    Packaging

    5 mL in glass bottle
    25, 100, 500 mL
    1, 2, 4 L in glass bottle
    The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

    Application

    Catalyst used in the preparation of cyclopentyl- and cycloheptyl[b]indoles from aryl cyclopropyl ketones via [3+2] cycloaddition.[1]
    Lewis acid reagent with broad application

    Legal Information

    Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

    SAFETY INFORMATION

    Signal Word

    Danger

    Hazard Statements

    H226 - H302 + H332 - H314 - H372 - H412

    Precautionary Statements

    P210 - P273 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

    Hazard Classifications

    Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - STOT RE 1 Inhalation

    Target Organs

    Kidney

    Storage Class Code

    3 - Flammable liquids

    WGK

    WGK 1

    Flash Point(F)

    137.3 °F - closed cup

    Flash Point(C)

    58.5 °C - closed cup

    Personal Protective Equipment

    dust mask type N95 (US), Eyeshields, Gloves