Acetone-d6, 10mL

SKU:
444863-10ML-GL
  • $55.60

    • Description

    Acetone-d6

    99.9 atom % D

    Synonym(s):
    Hexadeuteroacetone
    Linear Formula:
    CD3COCD3
    CAS Number:
    666-52-4
    Molecular Weight:
    64.12
    Beilstein:
    1702935
    EC Number:
    211-563-9
    MDL number:
    MFCD00044635
    PubChem Substance ID:
    24868149

    PROPERTIES

    vapor density

    2 (vs air)

    Quality Level

    100

    vapor pressure

    14.39 psi ( 55 °C)
    184 mmHg ( 20 °C)
    3.67 psi ( 20 °C)

    isotopic purity

    99.9 atom % D

    Assay

    ≥99% (CP)

    form

    liquid

    expl. lim.

    13.2 %

    packaging

    Sure/Seal™ of 100 mL
    ampule of 0.5 mL, 0.6 mL, 10 mL
    glass bottle of 10, 25, 50 mL

    technique(s)

    GC/MS: suitable
    NMR: suitable

    impurities

    ≤0.0500% water
    water

    refractive index

    n20/D 1.355 (lit.)

    bp

    55.5 °C (lit.)

    mp

    −93.8 °C (lit.)

    density

    0.872 g/mL at 25 °C (lit.)

    mass shift

    M+6

    SMILES string

    [2H]C([2H])([2H])C(=O)C([2H])([2H])[2H]

    InChI

    1S/C3H6O/c1-3(2)4/h1-2H3/i1D3,2D3

    InChI key

    CSCPPACGZOOCGX-WFGJKAKNSA-N

    DESCRIPTION

    General description

    Acetone-d6 is a deuterated NMR solvent useful in NMR-based research and analyses. Its Infrared and Raman spectra have been analyzed.[1] Pyrolysis and photolysis of acetone-d6 and methane mixtures have been investigated as a function of temperature.[2] It has been reported to be prepared by reacting heavy water with propyne-d4 in the presence of mercury catalyst.[3]

    Application

    Acetone-d6 may be used as an internal standard to detect aldehydes and acetone in water by headspace-solid-phase microextraction and gas chromatography-mass spectrometry.[4]

    Legal Information

    Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

    SAFETY INFORMATION

    Signal Word

    Danger

    Hazard Statements

    H225 - H319 - H336

    Precautionary Statements

    P210 - P233 - P240 - P241 - P242 - P305 + P351 + P338

    Hazard Classifications

    Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

    Target Organs

    Central nervous system

    Supplementary Hazards

    EUH066

    Storage Class Code

    3 - Flammable liquids

    WGK

    WGK 1

    Flash Point(F)

    -2.2 °F - closed cup

    Flash Point(C)

    -19 °C - closed cup

    Personal Protective Equipment

    dust mask type N95 (US), Eyeshields, Gloves