Triethylaluminum solution, 100ML

SKU:
252662-100ML
  • $134.00

    • Description

    Triethylaluminum solution

    1.0 M in hexanes

    Synonym(s):
    Aluminumtriethanide
    Linear Formula:
    Al(C2H5)3
    CAS Number:
    97-93-8
    Molecular Weight:
    114.16
    Beilstein/REAXYS Number:
    3587229
    MDL number:
    MFCD00009015
    PubChem Substance ID:
    24855229
    NACRES:
    NA.22

    PROPERTIES

    form

    liquid

    Quality Level

    100

    concentration

    1.0 M in hexanes

    density

    0.692 g/mL at 25 °C

    SMILES string

    CC[Al](CC)CC

    InChI

    1S/3C2H5.Al/c3*1-2;/h3*1H2,2H3;

    InChI key

    VOITXYVAKOUIBA-UHFFFAOYSA-N

    DESCRIPTION

    Application

    Triethylaluminum solution can be used:
    • As a reagent in Alumino-Mannich reaction, where it reacts with iminium ion substrates for which the corresponding Petasis borono-Mannich reaction is unsuccessful.[1]
    • In the synthesis of macrocyclic binuclear aluminum complexes with efficient activities toward ring-opening polymerization of ε-caprolactone.[2]
    • To promote Claisen rearrangement of allyl vinyl ether derivatives along with the transfer of ethyl group to aldehydic carbon.[3]
    • As a reagent for copper-catalyzed asymmetric conjugate addition of alkenyl- and alkylalanes to α,β-unsaturated lactams.[4]
    • As a precursor to synthesize diethylaluminium cyanide, which is used as hydrocyanating reagent.[5]

    SAFETY INFORMATION

    pictograms

    GHS02,GHS05,GHS07,GHS08,GHS09

    signalword

    Danger

    hcodes

    H225 - H250 - H252 - H260 - H304 - H314 - H336 - H361f - H411

    pcodes

    P210 - P231 + P232 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P370 + P378

    Hazard Classifications

    Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Repr. 2 - Self-heat. 2 - Skin Corr. 1A - STOT SE 3 - Water-react 1

    target_organs

    Respiratory system

    supp_hazards

    EUH014

    Storage Class

    4.2 - Pyrophoric and self-heating hazardous materials

    wgk_germany

    WGK 3

    flash_point_f

    -0.4 °F - closed cup

    flash_point_c

    -18 °C - closed cup

    ppe

    Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter