Toluene ACS reagent, 1L

SKU:
179418-1L
  • $84.10

    • Description

    179418 Sigma-Aldrich

    Toluene

    ACS reagent, ≥99.5%

    • CAS Number 108-88-3

       

    • Linear Formula C6H5CH3

       

    • Molecular Weight 92.14

       

    •  Beilstein/REAXYS Number 635760

       

    •  EC Number 203-625-9

       

    •  MDL number MFCD00008512

       

    •  eCl@ss 39011102

       

    •  PubChem Substance ID 329751592

       

    •  NACRES NA.21

    Description

    General description

    Toluene, a flammable liquid with a pungent odor, is widely employed as organic solvent. It is widely used as a precursor for synthesizing benzene and as a solvent in the paint industry.[6] It has been reported to be a biotoxic solvent (toxic to many microorganisms at 0.1%v/v concentrations).[1] Its anaerobic biodegradation to CO2, by the denitrifying bacterium Thauera arornatica has been reported.[2] It forms a syndiotactic polystyrene-toluene molecular compound. Crystal structure of this molecular compound has been investigated by X-ray diffraction studies.[3]

    Application

    Toluene has been employed as an solvent for the asymmetric synthesis of propargylic alcohols via addition reaction of terminal alkynes with various aldehydes in the presence of an optically active reagent, N-methylephedrine.[4] It may be used in the preparation of amine-capped gold nanocrystals.[5] Toluene undergoes alkylation in the presence of modified ZSM (Zeolite Socony Mobil)-5-class zeolite catalysts to form p-xylene with high selectivity.[8] When doped on graphene, it acts as an electron donor leading to alteration in graphene electrical properties.[7]

    Packaging

    1, 6×1, 2.5, 4×2.5, 4, 4×4 L in glass bottle

    View returnable container options.

    18, 20, 200 L in steel drum

    500, 6×500 mL in glass bottle

    Properties

    Related Categories ACS Grade, ACS Grade Solvents, ACS and Reagent Grade Solvents, Amber Glass Bottles, Carbon Steel Cans with NPT Threads,
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    Quality Level   200
    grade   ACS reagent
    vapor density   3.2 (vs air)
    vapor pressure   22 mmHg ( 20 °C)
      26 mmHg ( 25 °C)
    assay   ≥99.5%
    autoignition temp.   997 °F
    expl. lim.   7 %
    impurities   H2SO4, passes test (darkened)
      ≤0.003% S compounds
      ≤0.030% water
    evapn. residue   ≤0.0010%
    color   APHA: ≤10
    refractive index   n/D 1.496 (lit.)
    bp   110-111 °C (lit.)
    mp   -93 °C (lit.)
    density   0.865 g/mL at 25 °C (lit.)
    SMILES string   Cc1ccccc1
    InChI   1S/C7H8/c1-7-5-3-2-4-6-7/h2-6H,1H3
    InChI key   YXFVVABEGXRONW-UHFFFAOYSA-N