alpha-Phellandrene (5mL)

SKU:
77429-5ML
  • $145.00

    • Description

    77429 Sigma-Aldrich

    (R)-(−)-α-Phellandrene

    ≥95.0% (sum of enantiomers, GC)

    Synonym: (−)-p-Mentha-1,5-diene, (R)-(-)-alpha-Phellandrene, (R)-5-Isopropyl-2-methyl-1,3-cyclohexadiene

    • CAS Number 4221-98-1

       

    • Empirical Formula (Hill Notation) C10H16

       

    • Molecular Weight 136.23

       

    •  Beilstein Registry Number 2497824

       

    •  EC Number 224-167-6

    •  MDL number MFCD00062988

       

    Description

    Packaging

    1, 5 mL in glass bottle

    Application

    (R)-(-)-α-Phellandrene undergoes [4+2] cycloaddition with 2-naphthyl acetylenecarboxylate to form a chiral diene, which can act as a ligand for the rhodium-catalyzed asymmetric addition reactions.[2] It may be used to synthesize (1S,5R)-5-(1-methylethyl)-2-methylidene-3-cyclohexen-1-yl hydroperoxide, which on reduction forms trans-yabunikkeol.[3]

    General description

    (R)-(-)-α-Phellandrene is a monoterpene derivative.[1]

    Properties

    Related Categories Alkenes, Allium sativum (Garlic), Artemisia vulgaris,Asymmetric Synthesis, Boswellia carterii,
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    InChI Key OGLDWXZKYODSOB-SNVBAGLBSA-N
    assay ≥95.0% (sum of enantiomers, GC)
    optical activity [α]20/D −225±5°, c = 10% in diethyl ether
    bp 171-174 °C(lit.)
    density 0.844 g/mL at 20 °C(lit.)
    storage temp. 2-8°C