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Diethylaluminum chloride solution 800mL, 1EA

SKU:
212806-800ML
  • $345.00

    • Description

    Diethylaluminum chloride solution

    Synonym(s):
    Chlorodiethylaluminum, Dichlorotetraethyldialuminium, Diethylaluminum monochloride
    Linear Formula:
    (C2H5)2AlCl
    CAS Number:
    96-10-6
    Molecular Weight:
    120.56
    Beilstein:
    4123259
    MDL number:
    MFCD00000459
    PubChem Substance ID:
    24852743
    NACRES:
    NA.22

    PROPERTIES

    form

    liquid

    Quality Level

    200

    concentration

    1.0 M in hexanes

    density

    0.711 g/mL at 25 °C

    SMILES string

    CC[Al](Cl)CC

    InChI

    1S/2C2H5.Al.ClH/c2*1-2;;/h2*1H2,2H3;;1H/q;;+1;/p-1

    InChI key

    YNLAOSYQHBDIKW-UHFFFAOYSA-M

    Application

    Diethylaluminum chloride solution can be used:
    • As a Lewis acid for the synthesis of Lewis acid-base bifunctional asymmetric catalysts for cyanosilylation of aldehydes[1] and in Strecker reaction.[2]
    • For the synthesis of precursors for lanthanide/aluminum catalysts for diene polymerization.[3]
    • As a co-initiator in the cationic polymerization of isobutylene.[4]

    Packaging

    The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

    Legal Information

    Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

    SAFETY INFORMATION

    Pictograms

    GHS02,GHS05,GHS07,GHS08,GHS09

    Signal Word

    Danger

    Hazard Statements

    H225 - H250 - H260 - H304 - H314 - H336 - H361f - H411

    Precautionary Statements

    P210 - P231 + P232 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P370 + P378

    Hazard Classifications

    Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Repr. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1

    Target Organs

    Central nervous system

    Storage Class Code

    4.2 - Pyrophoric and self-heating hazardous materials

    WGK

    WGK 3

    Flash Point(F)

    -7.6 °F

    Flash Point(C)

    -22 °C

    Personal Protective Equipment

    dust mask type N95 (US), Eyeshields, Gloves