Description
Potassium dichromate, 100G
Synonym(s):
Potassium bichromate
Linear Formula:
K2Cr2O7
CAS Number:
7778-50-9
Molecular Weight:
294.18
EC Number:
231-906-6
MDL number:
MFCD00011367
PubChem Substance ID:
329752023
NACRES:
NB.24
PROPERTIES
grade
ACS reagent
Quality Level
200
assay
≥99.0%
form
crystals
reaction suitability
reagent type: oxidant
impurities
≤0.005% insolubles
loss
≤0.05% loss on drying
pH
3.5-5.0 (25 °C, 29.4 g/L)
mp
398 °C (lit.)
anion traces
chloride (Cl-): ≤0.001%
sulfate (SO42-): ≤0.005%
cation traces
Ca: ≤0.003%
Na: ≤0.001%
Na: ≤0.02%
heavy metals (as Pb): ≤5 ppm
SMILES string
[K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O
InChI
1S/2Cr.2K.7O/q;;2*+1;;;;;;2*-1
InChI key
KMUONIBRACKNSN-UHFFFAOYSA-N
DESCRIPTION
General description
Potassium dichromate is a red-orange colored solid. Its crystals belong to the triclinic crystal system. On heating above 600°C, it decomposes to give oxygen, potassium chromate and chromium(III) oxide. It acts as a strong oxidizing agent in acidic media. It can be synthesized by the fusion of chromium(III) oxide with potassium carbonate and nitrate or oxygen.[1]
Application
Potassium dichromate may be used in the preparation of hybride polymer-clay nanocomposite supported dichromate reagents.[2] It may also be used as an oxidant for the selective oxidation of primary and secondary alcohol to corresponding aldehydes and ketones, respectively.[3]
Packaging
100, 500 g in poly bottle
SAFETY INFORMATION
Signal Word
Danger
Hazard Statements
H272 - H301 - H312 - H314 - H317 - H330 - H334 - H335 - H340 - H350 - H360FD - H372 - H410
Precautionary Statements
P210 - P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
Hazard Classifications
Acute Tox. 2 Inhalation - Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B - Eye Dam. 1 - Muta. 1B - Ox. Sol. 2 - Repr. 1B - Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1 - STOT RE 1 Inhalation - STOT SE 3
Target Organs
Cardio-vascular system, Respiratory system
Storage Class Code
5.1B - Oxidizing hazardous materials
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable