OXONE, monopersulfate compound, 1K

SKU:
228036-1KG
  • $79.30

    • Description

    OXONE®, monopersulfate compound, 1K

    Synonym(s):
    Potassium peroxymonosulfate
    Linear Formula:
    KHSO5 · 0.5KHSO4 · 0.5K2SO4
    CAS Number:
    70693-62-8
    Molecular Weight:
    307.38
    MDL number:
    MFCD00040551
    PubChem Substance ID:
    57648006
    NACRES:
    NA.21

    PROPERTIES

    vapor pressure

    <0.0000017 hPa

    Quality Level

    200

    form

    powder

    reaction suitability

    reagent type: oxidant

    concentration

    >4.0% (active oxygen basis (by Na2S2O3, titration))

    pH

    2.1 (77 °C, 30 g/L)

    SMILES string

    [K+].[K+].[K+].[K+].[K+].OS([O-])(=O)=O.[O-]S([O-])(=O)=O.O[S+]([O-])([O-])(=O)=O.O[S+]([O-])([O-])(=O)=O

    InChI

    1S/5K.2H2O5S.2H2O4S/c;;;;;2*1-5-6(2,3)4;2*1-5(2,3)4/h;;;;;2*1H,(H,2,3,4);2*(H2,1,2,3,4)/q5*+1;;;;/p-5

    InChI key

    HJKYXKSLRZKNSI-UHFFFAOYSA-I

    General description

    OXONE®, monopersulfate compound is a potassium triple salt mainly used as a stable, easy to handle and nontoxic oxidant.[1]

    Application

    A rapid, efficient synthesis of oxaziridines from imines using buffered OXONE has been reported.[2] Also used to study fading of an artist′s colorants.[3]
    OXONE®, monopersulfate compound may be used as an alternative to transition-metal oxidants for the conversion of aldehydes to carboxylic acids or esters.[1]
    Oxidant used for halogenation of α,β-unsaturated carbonyl compounds and catalytic generation of hypervalent iodine reagents for alcohol oxidation.
    Oxidant used for halogenation of a,b-unsaturated carbonyl compounds and catalytic generation of hypervalent iodine reagents for alcohol oxidation.

    Legal Information

    OXONE is a registered trademark of E. I. du Pont de Nemours and Company