Description
251380 Sigma-Aldrich
L-(+)-Tartaric acid
ACS reagent, ≥99.5%
Synonym: (2R,3R)-(+)-Tartaric acid, L-Threaric acid
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CAS Number 87-69-4
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Linear Formula HO2CCH(OH)CH(OH)CO2H
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Molecular Weight 150.09
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Beilstein/REAXYS Number 1725147
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EC Number 201-766-0
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MDL number MFCD00064207
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PubChem Substance ID 24855129
Description
Application
L-(+)-Tartaric acid may be used in the synthesis of (R,R)-1,2-diammoniumcyclohexane mono-(+)-tartrate, an intermediate to prepare an enantioselective epoxidation catalyst.[7] It may also be used as a starting material in the multi-step synthesis of 1,4-di-O-benzyl-L-threitol.[8] It can be used a chiral resolving agent for the resolution of 2,2′-bispyrrolidine.[9]
Chiral building block for natural products.[1] Also forms a Diels-Alder catalyst with TiCl2(O-i-Pr)2.[2]
Packaging
100, 500 g in poly bottle
2.5 kg in poly bottle
5 g in glass bottle
Properties
Related Categories | Acids, Acids & Bases, Asymmetric Synthesis, Biochemicals and Reagents, Carboxylic Acids, |
grade | ACS reagent |
vapor density | 5.18 (vs air) |
InChI Key | FEWJPZIEWOKRBE-JCYAYHJZSA-N |
assay | ≥99.5% |
form | crystalline powder |
crystals | |
optical activity | [α]20/D +12.4°, c = 20 in H2O |
optical purity | ee: 99% (GLC) |
autoignition temp. | 797 °F |
impurities | ≤0.002% S compounds |
≤0.005% insolubles | |
ign. residue | ≤0.02% |
mp | 170-172 °C (lit.) |
anion traces | chloride (Cl-): ≤0.001% |
oxalate (C2O42-): passes test | |
phosphate (PO43-): ≤0.001% | |
cation traces | Fe: ≤5 ppm |
heavy metals (as Pb): ≤5 ppm |