Tartaric acid ACS reagent, (500g)

SKU:
251380-500G
  • $131.00

    • Description

    251380 Sigma-Aldrich

    L-(+)-Tartaric acid

    ACS reagent, ≥99.5%

    Synonym: (2R,3R)-(+)-Tartaric acid, L-Threaric acid

    • CAS Number 87-69-4

       

    • Linear Formula HO2CCH(OH)CH(OH)CO2H

       

    • Molecular Weight 150.09

       

    •  Beilstein/REAXYS Number 1725147

       

    •  EC Number 201-766-0

       

    •  MDL number MFCD00064207

       

    •  PubChem Substance ID 24855129

    Description

    Application

    L-(+)-Tartaric acid may be used in the synthesis of (R,R)-1,2-diammoniumcyclohexane mono-(+)-tartrate, an intermediate to prepare an enantioselective epoxidation catalyst.[7] It may also be used as a starting material in the multi-step synthesis of 1,4-di-O-benzyl-L-threitol.[8] It can be used a chiral resolving agent for the resolution of 2,2′-bispyrrolidine.[9]

    Chiral building block for natural products.[1] Also forms a Diels-Alder catalyst with TiCl2(O-i-Pr)2.[2]

    Packaging

    100, 500 g in poly bottle

    2.5 kg in poly bottle

    5 g in glass bottle

    Properties

    Related Categories Acids, Acids & Bases, Asymmetric Synthesis, Biochemicals and Reagents, Carboxylic Acids,
    More...
    grade   ACS reagent
    vapor density   5.18 (vs air)
    InChI Key   FEWJPZIEWOKRBE-JCYAYHJZSA-N
    assay   ≥99.5%
    form   crystalline powder
      crystals
    optical activity   [α]20/D +12.4°, c = 20 in H2O
    optical purity   ee: 99% (GLC)
    autoignition temp.   797 °F
    impurities   ≤0.002% S compounds
      ≤0.005% insolubles
    ign. residue   ≤0.02%
    mp   170-172 °C (lit.)
    anion traces   chloride (Cl-): ≤0.001%
      oxalate (C2O42-): passes test
      phosphate (PO43-): ≤0.001%
    cation traces   Fe: ≤5 ppm
      heavy metals (as Pb): ≤5 ppm