DPPF, 10G

SKU:
177261-10G
  • $212.00

    • Description

    DPPF, 10G
    Synonym(s):
    1,1′-Ferrocenediyl-bis(diphenylphosphine), dppf
    Empirical Formula (Hill Notation):
    C34H28FeP2
    CAS Number:
    12150-46-8
    Molecular Weight:
    554.38
    MDL number:
    MFCD00001422
    PubChem Substance ID:
    24850625
    NACRES:
    NA.22

    PROPERTIES

    Quality Level

    200

    assay

    97%

    form

    powder

    reaction suitability

    reagent type: catalyst
    reaction type: Cross Couplings
    reagent type: ligand
    reaction type: Buchwald-Hartwig Cross Coupling Reaction
    reagent type: ligand
    reaction type: Carbonylations
    reagent type: ligand
    reaction type: Ene Reaction
    reagent type: ligand
    reaction type: Heck Reaction
    reagent type: ligand
    reaction type: Negishi Coupling
    reagent type: ligand
    reaction type: Sonogashira Coupling
    reagent type: ligand
    reaction type: Stille Coupling
    reagent type: ligand
    reaction type: Suzuki-Miyaura Coupling
    reagent type: ligand
    reaction type: Tsuji-Trost Reaction

    greener alternative product characteristics

    Catalysis
    Learn more about the Principles of Green Chemistry.

    mp

    181-182 °C (dec.) (lit.)

    functional group

    phosphine

    greener alternative category

    Aligned

    SMILES string

    [Fe].[CH]1[CH][CH][C]([CH]1)P(c2ccccc2)c3ccccc3.[CH]4[CH][CH][C]([CH]4)P(c5ccccc5)c6ccccc6

    InChI

    1S/2C17H14P.Fe/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;/h2*1-14H;

    InChI key

    HPXNTHKXCYMIJL-UHFFFAOYSA-N

    General description

    Novel functionalized furan derivatives were prepared via Pd-phosphine sequential C-C and C-O bond formation.
    We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

    Application

    Ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing.

    Ruthenium-Catalyzed N-Alkylation of Amines and Sulfonamides Using Borrowing Hydrogen Methodology
    Ligand used in a Pd(II)-catalyzed cross-coupling synthesis of oxazepine ring systems.

    Packaging

    1, 10, 25 g in glass bottle

    SAFETY INFORMATION

    Storage Class Code

    13 - Non Combustible Solids

    WGK

    WGK 3

    Flash Point(F)

    Not applicable

    Flash Point(C)

    Not applicable

    Personal Protective Equipment

    dust mask type N95 (US), Eyeshields, Gloves