Dimethyl sulfoxide for HPLC, (1L)

SKU:
34869-1L
  • $282.00
  • Description

    34869 Sigma-Aldrich

    Dimethyl sulfoxide

    for HPLC, ≥99.7%

    Synonym: DMSO

    • CAS Number 67-68-5

       
    • Linear Formula (CH3)2SO

       
    • Molecular Weight 78.13

       
    •  Beilstein Registry Number 506008

       
    •  EC Number 200-664-3

       
    •  MDL number MFCD00002089

    Properties

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    More...
    grade for HPLC
    vapor density 2.7 (vs air)
    vapor pressure 0.42 mmHg ( 20 °C)
    InChI Key IAZDPXIOMUYVGZ-UHFFFAOYSA-N
    assay ≥99.7%
    autoignition temp. 573 °F
    expl. lim. 42 %, 63 °F
    impurities ≤0.002% non-volatile matter
     - ≤0.2% water (Karl Fischer)
    transmittance 270 nm, ≥20%
    280 nm, ≥50%
    300 nm, ≥80%
    350 nm, ≥98%
    refractive index n20/D 1.479(lit.)
    bp 189 °C(lit.)
    mp 16-19 °C (lit.)
    density 1.10 g/mL(lit.)

    Description

    Caution

    Supercools easily and remelts slowly at room temperature. Solidified product can be re-liquified by warming to room temperature without detriment to the product.

    Packaging

    1, 6×1, 2, 4×2, 4×4 L in glass bottle

    20 L in Nowpak™

    100, 12×100, 500 mL in glass bottle

    50 L in composite drum

    Application

    Suitable for HPLC, spectrophotometry, environmental testing

    General description

    Dimethyl sulfoxide (DMSO) is a polar organic solvent.[1] DMSO activated by various electrophiles (oxalyl chloride) has been used to oxidize various alcohols (primary, secondary, allylic, benzylic, hindered and bicyclic). Carbonyl compounds are formed as reaction products.[2] Due to its higher stability, it has been proposed as an alternate solvent for methyl cellosolve for use in ninhydrin reaction.[3]

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