Chloroform-d, 100G

SKU:
151823-100G
  • $61.60

    • Description

    Chloroform-d, 100G

    99.8 atom % D

    Synonym(s):
    Deuterochloroform
    Linear Formula:
    CDCl3
    CAS Number:
    865-49-6
    Molecular Weight:
    120.38
    Beilstein:
    1697633
    EC Number:
    212-742-4
    MDL number:
    MFCD00000827
    PubChem Substance ID:
    24849167
    NACRES:
    NA.21

    PROPERTIES

    Quality Level

    200

    isotopic purity

    99.8 atom % D

    assay

    ≥99% (CP)

    form

    liquid

    technique(s)

    NMR: suitable

    refractive index

    n20/D 1.444 (lit.)

    bp

    60.9 °C (lit.)

    mp

    −64 °C (lit.)

    density

    1.500 g/mL at 25 °C (lit.)

    mass shift

    M+1

    SMILES string

    [2H]C(Cl)(Cl)Cl

    InChI

    1S/CHCl3/c2-1(3)4/h1H/i1D

    InChI key

    HEDRZPFGACZZDS-MICDWDOJSA-N

    General description

    Chloroform-d (Deuterochloroform, CDCl3), deuterated chloroform, is a standard purity solvent for NMR (Nuclear Magnetic Resonance) analyses. It is widely employed in high resolution NMR studies due to its high chemical and isotopic purity. Quantitaive infrared spectral investigations of carbon-deuterium stretching bands of chloroform-d in various organic solvents have been reported. Raman difference spectroscopic studies of mixtures of chloroform-d and liquid chloroform have been conducted to evaluate frequency shifts in the ν1 and ν2 bands of CHCl3 and CDCl3.

    Application

    Chloroform-d has been employed as solvent in a 1H NMR (Proton Nuclear Magnetic Resonance) spectroscopic study. It has been employed as solvent during the 31PNMR (Phosphorus-31 nuclear magnetic resonance) spectral investigation of triphenyl phosphate and tris(2-chloroethyl) phosphate. It has also been used as the deuterated solvent in the 1H NMR spectral studies of 2-(4-bromobenzyl)-3-hydroxypropanoic acid and 3-hydroxy-2-(4-methoxybenzyl)propanoic acid. It has also been used as the deuterated solvent for the 1HNMR spectral studies of 3,3′-dihydroxy-4,4′-diamino-biphenyl (HAB) and 2,2′-bis-(3,4-dicarboxy-phenyl) hexafluoropropane dianhydride (6FDA) polyimide.

    Packaging

    10×0.6, 10×0.75, 10×1 mL in ampule
    50, 100, 250 g in glass bottle
    1 kg in glass bottle

    SAFETY INFORMATION

    Signal Word

    Danger

    Hazard Statements

    H302 - H315 - H319 - H331 - H336 - H351 - H361d - H372

    Precautionary Statements

    P202 - P301 + P312 - P302 + P352 - P304 + P340 + P311 - P305 + P351 + P338 - P308 + P313

    Hazard Classifications

    Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 1 Oral - STOT SE 3

    Target Organs

    Central nervous system

    Storage Class Code

    6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

    WGK

    WGK 3

    Personal Protective Equipment

    dust mask type N95 (US), Eyeshields, Gloves