Description
156264 Sigma-Aldrich
Ammonium formate
reagent grade, 97%
Synonym: Formic acid ammonium salt
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CAS Number 540-69-2
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Linear Formula HCO2NH4
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Molecular Weight 63.06
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Beilstein Registry Number 3625095
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EC Number 208-753-9
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MDL number MFCD00013103
Description
Packaging
1, 2.5 kg in poly bottle
100, 500 g in poly bottle
Application
Ammonium formate may be employed in the following studies:
• Deprotection of N-benzyl derivatives of amino acids and amines to afford free amino acids and amines.[2]
• Conversion of α, β-unsaturated nitroalkenes to the corresponding oximes.[4]
• Preparation of nitriles.[5]
General description
Ammonium formate is an ammonium salt of formic acid. It is a cheap and promising N-formylating agent for various amines (secondary and aniline).[3] Its anhydrous form may be employed as a catalyst for the synthesis of various amino derivatives from aliphatic and aromatic compounds.[1]
Ammonium formate can be used as a source to produce ammonia.[7] It can also be used in the reductive alkylation of amines.[6]
Properties
Related Categories | Ammonium Salts, Essential Chemicals, Research Essentials, Salts |
grade | reagent grade |
InChI Key | VZTDIZULWFCMLS-UHFFFAOYSA-N |
assay | 97% |
mp | 119-121 °C (lit.) |
density | 1.26 g/mL at 25 °C(lit.) |