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Ammonium formate reagent grade, 100g

SKU:
156264-100G
  • $47.70
  • Description

    156264 Sigma-Aldrich

    Ammonium formate

    reagent grade, 97%

    Synonym: Formic acid ammonium salt

    • CAS Number 540-69-2

       
    • Linear Formula HCO2NH4

       
    • Molecular Weight 63.06

       
    •  Beilstein Registry Number 3625095

       
    •  EC Number 208-753-9

       
    •  MDL number MFCD00013103

    Description

    Packaging

    1, 2.5 kg in poly bottle

    100, 500 g in poly bottle

    Application

    Ammonium formate may be employed in the following studies:
    • Deprotection of N-benzyl derivatives of amino acids and amines to afford free amino acids and amines.[2]
    • Conversion of α, β-unsaturated nitroalkenes to the corresponding oximes.[4]
    • Preparation of nitriles.[5]

    General description

    Ammonium formate is an ammonium salt of formic acid. It is a cheap and promising N-formylating agent for various amines (secondary and aniline).[3] Its anhydrous form may be employed as a catalyst for the synthesis of various amino derivatives from aliphatic and aromatic compounds.[1]
    Ammonium formate can be used as a source to produce ammonia.[7] It can also be used in the reductive alkylation of amines.[6]

    Properties

    Related Categories Ammonium Salts, Essential Chemicals, Research Essentials, Salts
    grade reagent grade
    InChI Key VZTDIZULWFCMLS-UHFFFAOYSA-N
    assay 97%
    mp 119-121 °C (lit.)
    density 1.26 g/mL at 25 °C(lit.)