Ammonium acetate, 100G

SKU:
73594-100G-F
  • $605.00
  • Description

    Ammonium acetate

    LiChropur, eluent additive for LC-MS

    CAS Number:
    631-61-8
    Molecular Weight:
    77.08
    Beilstein/REAXYS Number:
    4186741
    EC Number:
    211-162-9
    MDL number:
    MFCD00013066
    eCl@ss:
    39021908
    PubChem Substance ID:
    329765068
    NACRES:
    NB.21

    PROPERTIES

    InChI key

    USFZMSVCRYTOJT-UHFFFAOYSA-N

    grade

    eluent additive for LC-MS

    Quality Level

    100

    agency

    suitable for ASTM® 7968
    suitable for ASTM® 7979
    suitable for DIN 38407-42
    suitable for EPA 1633
    suitable for EPA 533
    suitable for EPA 537.1
    suitable for EPA 8327
    suitable for EPA ACB B21-02
    suitable for EPA ACB B23-05b
    suitable for GB 31604.35-2016
    suitable for GB 5009.253-2016
    suitable for ISO 21675 2019
    suitable for ISO 25101
    suitable for ISO/CEN 15968-2010

    reg. compliance

    suitable for FDA C-010.02

    assay

    ≥99.0% (calc. on dry substance, T)

    form

    solid

    quality

    LiChropur

    technique(s)

    LC/MS: suitable

    impurities

    insoluble matter, passes filter test
    ≤1% water

    ign. residue

    ≤0.01% (as SO4)

    pH

    6.2-7.5 (25 °C, 1 M in H2O)

    mp

    110-112 °C (dec.) (lit.)

    solubility

    H2O: 1 M at 20 °C, clear, colorless

    anion traces

    chloride (Cl-): ≤5 mg/kg
    nitrate (NO3-): ≤10 mg/kg
    sulfate (SO42-): ≤10 mg/kg

    cation traces

    Al: ≤1 mg/kg
    As: ≤0.1 mg/kg
    Ba: ≤1 mg/kg
    Bi: ≤1 mg/kg
    Ca: ≤5 mg/kg
    Cd: ≤1 mg/kg
    Co: ≤1 mg/kg
    Cr: ≤1 mg/kg
    Cu: ≤1 mg/kg
    Fe: ≤1 mg/kg
    K: ≤5 mg/kg
    Li: ≤1 mg/kg
    Mg: ≤1 mg/kg
    Mn: ≤1 mg/kg
    Mo: ≤1 mg/kg
    Na: ≤5 mg/kg
    Ni: ≤1 mg/kg
    Pb: ≤1 mg/kg
    Sr: ≤1 mg/kg
    Zn: ≤1 mg/kg

    SMILES string

    N.CC(O)=O

    λ

    1 M in H2O

    UV absorption

    λ: 260 nm Amax: ≤0.015
    λ: 280 nm Amax: ≤0.010

    suitability

    passes test for LC-MS

    InChI

    1S/C2H4O2.H3N/c1-2(3)4;/h1H3,(H,3,4);1H3

    General description

    Ammonium acetate exists as a white crystal. It is prepared from acetic acid and ammonia by neutralization to pH 7.0. It is widely used in analytical chemistry, drugs and in textile dyeing.[1]

    Application

    Ammonium acetate has been used to prepare eluents for UPLC-MS/MS and HPLC-MS/MS to compare the matrix effect of 9 pharmaceutical compounds in aqueous environmental samples.[2] It has also been used as an additive to improve detection of phosphopeptides using MALDI-MS.[3]

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    Legal Information

    ASTM is a registered trademark of American Society for Testing and Materials
    LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

    SAFETY INFORMATION

    Storage Class

    11 - Combustible Solids

    wgk_germany

    WGK 1

    flash_point_f

    Not applicable

    flash_point_c

    Not applicable

    ppe

    Eyeshields, Gloves, type N95 (US)